AN AZIDE-DIENE CYCLOADDITION APPROACH TO INDOLIZIDINE ALKALOIDS - AN ENANTIOSELECTIVE SYNTHESIS OF 6,7-DIEPICASTANOSPERMINE

被引：27

作者：

KIM, NS ^{[1
]}

KANG, CH ^{[1
]}

CHA, JK ^{[1
]}

机构：

[1] UNIV ALABAMA,DEPT CHEM,TUSCALOOSA,AL 35487

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 21期

关键词：

D O I：

10.1016/S0040-4039(00)73217-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A short, enantioselective synthesis of 6,7-diepicastanospermine (4) has been achieved by an intramolecular azide-diene 1,3-dipolar cycloaddition, followed by ring-opening of the vinylaziridine 6 and subsequent dihydroxylation.

引用

页码：3489 / 3492

页数：4

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