INTENSITIES OF LINES IN THE BANDS NU-2 AND NU-4 AND THE TRANSITION DIPOLE-MOMENTS OF PH3

被引：10

作者：

KSHIRSAGAR, RJ

SINGH, K

DCUNHA, R

JOB, VA

PAPOUSEK, D

OGILVIE, JF

FUSINA, L

机构：

[1] ACAD SINICA,INST ATOM & MOLEC SCI,TAIPEI 10764,TAIWAN

[2] DIPARTIMENTO CHIM FIS & INORGAN,I-40136 BOLOGNA,ITALY

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1991年 / 149卷 / 01期

关键词：

D O I：

10.1016/0022-2852(91)90149-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The absolute intensities of 57 vibration-rotational spectral lines of transitions to the vibrational states v2 = 1 and v4 = 1 of PH3 have been measured with a diode laser. With account being taken of the mixing of the wavefunctions of both vibrational states, the values of the vibrational transition moments and their relative signs were determined by a least-squares fit to the experimental data: 〈0, 00∥μz∥1, 00〉 = (0.23913 ± 0.00093) × 10-30C m and 〈0, 00∥μx∥0, 1±1〉 = -(0.14060 ± 0.00137) × 10-30C m. © 1991.

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页码：152 / 159

页数：8

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