ANALYSIS OF COPPER(I) STABILITY IN THE CATIONIC [CU(CH3CN)4-N(PH3P)N]+ SERIES OF COMPLEXES

被引：22

作者：

LEIVA, AM

RIVERA, L

LOEB, B

机构：

[1] Faculty of Chemistry, P. Catholic University of Chile, Santiago

来源：

POLYHEDRON | 1991年 / 10卷 / 03期

关键词：

D O I：

10.1016/S0277-5387(00)80155-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

NMR and electrochemical studies on the stability of copper(I) complexes of the type [Cu(CH3CN)4(-n)(Ph3P)(N)]+ (n = o-4) were carried out to explore the effect of phosphine ligands on stabilization. The effect of phosphine ligands was demonstrated by cyclic voltammetry and P-31 NMR. A correlation between structural and electronic effects and the stability of the complexes was established.

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页码：347 / 350

页数：4

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