VISCOSITY OF BINARY HEPTANE NONYLBENZENE AS A FUNCTION OF PRESSURE AND TEMPERATURE - APPLICATION OF FLORY THEORY

被引:63
作者
KANTI, M [1 ]
LAGOURETTE, B [1 ]
ALLIEZ, J [1 ]
BONED, C [1 ]
机构
[1] UNIV PAU & PAYS ADOUR,CURS,PHYS MAT IND LAB,AVE UNIV,F-64000 PAU,FRANCE
关键词
D O I
10.1016/0378-3812(91)87031-4
中图分类号
O414.1 [热力学];
学科分类号
摘要
The dynamic viscosity and density of the n-heptane + nonylbenzene binary mixture have been measured as a function of concentration, between 1 and 400 bar at temperatures 40, 60 and 80-degrees-C. The 105 experimental values were adjusted by means of the Bloomfield and Dewan relationship and Flory's theory, without employing any additional adjustable parameters. The mean deviation observed is 5.7%. This shows that the range of applicability of this representation, tested successfully at atmospheric pressure, can be extended to conditions of higher pressure. For comparison, the experimental results have been tested against other laws, representative of the viscosity of mixtures, relying upon an adjustable empirical parameter.
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页码:291 / 304
页数:14
相关论文
共 25 条
[1]   THERMODYNAMIC PROPERTIES OF MIXTURES OF SMALL NONPOLAR MOLECULES [J].
ABE, A ;
FLORY, PJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (09) :1838-&
[2]   THERMODYNAMIC PROPERTIES OF BINARY-MIXTURES OF ISOOCTANE AND NORMAL-ALKANE AT 298.15-K [J].
AWWAD, AM ;
ALLOS, EI .
FLUID PHASE EQUILIBRIA, 1985, 22 (03) :353-365
[3]   VOLUMES AND VISCOSITIES OF BENZENE + N-ALKANE MIXTURES [J].
AWWAD, AM ;
ALAZZAWI, SF ;
SALMAN, MA .
FLUID PHASE EQUILIBRIA, 1986, 31 (02) :171-182
[4]   VISCOSITY OF LIQUID MIXTURES [J].
BLOOMFIELD, VA ;
DEWAN, RK .
JOURNAL OF PHYSICAL CHEMISTRY, 1971, 75 (20) :3113-+
[5]   APPAREILLAGE DE MESURE DE LA VISCOSITE SOUS TRES HAUTE PRESSION [J].
CHARLES, E ;
GROUBERT, E .
REVUE DE PHYSIQUE APPLIQUEE, 1966, 1 (04) :303-&
[6]   VISCOSITIES OF MIXTURES OF BRANCHED AND NORMAL ALKANES WITH TETRABUTYLTIN - EFFECT OF ORIENTATIONAL ORDER OF LONG-CHAIN ALKANES ON ENTROPY OF MIXING [J].
DELMAS, G ;
PURVES, P ;
SAINTROMAIN, PD .
JOURNAL OF PHYSICAL CHEMISTRY, 1975, 79 (18) :1970-1974
[7]   FALLING BODY VISCOSIMETER FOR HIGH-PRESSURE VISCOSITY MEASUREMENTS [J].
DUCOULOMBIER, D ;
LAZARRE, F ;
STGUIRONS, H ;
XANS, P .
REVUE DE PHYSIQUE APPLIQUEE, 1985, 20 (10) :735-740
[8]  
DUCOULOMBIER D, 1986, J PHYS CHEM-US, V90, P1692, DOI 10.1021/j100399a047
[9]  
Dymond J. H., 1980, International Journal of Thermophysics, V1, P345
[10]  
DYMOND JH, 1981, INT J THERMOPHYS, V2, P223, DOI DOI 10.1007/BF00504186