NEMOROSONOL, A DERIVATIVE OF TRICYCLO-[4.3.1.03,7]-DECANE-7-HYDROXY-2,9-DIONE FROM CLUSIA-NEMOROSA .7.

被引：31

作者：

CERRINI, S

LAMBA, D

DELLEMONACHE, F

PINHERIO, RM

机构：

[1] CNR, IST STRUTTURIST CHIM G GIACOMELLO, CPN 10, I-00016 MONTEROTONDO, ITALY

[2] UNIV CATTOLICA SACRO CUORE, CNR, CTR CHIM RECETTORI & MOLECOLE BIOL ATT, I-00168 ROME, ITALY

[3] UNIV FED ALOGOAS, DEPT QUIM, BR-57000 MACEIO, BRAZIL

来源：

PHYTOCHEMISTRY | 1993年 / 32卷 / 04期

关键词：

CLUSIA-NEMOROSA; GUTTIFERAE; FRUITS; NEMOROSONOL; POLYISOPRENYLATED BENZOPHENONE; X-RAY CRYSTAL STRUCTURE;

D O I：

10.1016/0031-9422(93)85248-P

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The structure and relative stereochemistry of nemorosonol, isolated from the fruits of Clusia nemorosa, has been determined by X-ray crystallography. The novelty of the nemorosonol structure consists in its unique tricyclo[4.3. 1.0(3,7)]-decane-2,9-dione moiety. There are two crystallographically independent molecules in the unit cell, which show a different orientation of the isoprenyl side chain at C-1. The relative stereochemistry at C-5 has been revised. The molecules are held together by hydrogen bonding to form chains along the c axis.

引用

页码：1023 / 1028

页数：6

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