PHOTOCHEMICAL NITRATION BY TETRANITROMETHANE .14. THE FORMATION OF 1,3-DIPOLAR NITRO ADDITION-PRODUCTS FROM THE PHOTOCHEMICAL-REACTION OF 1,2-DIMETHYLNAPHTHALENE AND TETRANITROMETHANE

被引：13

作者：

BUTTS, CP

CALVERT, JL

EBERSON, L

HARTSHORN, MP

MACLAGAN, RGAR

ROBINSON, WT

机构：

[1] LUND UNIV,CTR CHEM,POB 124,S-22100 LUND,SWEDEN

[2] UNIV CANTERBURY,DEPT CHEM,CHRISTCHURCH 1,NEW ZEALAND

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1994年 / 47卷 / 06期

关键词：

D O I：

10.1071/CH9941087

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photolysis of the 1,2-dimethylnaphthalene/tetranitromethane charge-transfer complex yields the triad of 1,2-dimethylnaphthalene radical cation, nitrogen dioxide, and trinitromethanide ion. Recombination of this triad gives predominantly the adducts (13)-(16), each of which is formed by attack of the trinitromethanide ion at C4 of the 1,2-dimethylnaphthalene radical cation. Thermal cycloaddition in adducts (13) and (16) gives the cycloadducts (12) and (17) respectively.

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页码：1087 / 1096

页数：10

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