A STABLE 6-METALATED 1-AZAFULVENE - SYNTHESIS AND REACTIONS OF RU(C[C4H3N]SCNME2S)(ETA-2-S2CNME2)(CO)(PPH3) AND CRYSTAL-STRUCTURE OF [RU(=C(SCNME2S)(2-PYRROLYL))-(ETA-2-S2CNME2)(CO)(PPH3)]+

被引：9

作者：

IRVINE, GJ ^{[1
]}

RICKARD, CEF ^{[1
]}

ROPER, WR ^{[1
]}

WRIGHT, LJ ^{[1
]}

机构：

[1] UNIV AUCKLAND,DEPT CHEM,AUCKLAND,NEW ZEALAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 387卷 / 01期

关键词：

D O I：

10.1016/0022-328X(90)87309-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Dimethyldithiocarbamate displaces chloride from both the carbene centre and the metal in Ru[CCl(2-pyrrolyl)]Cl2(CO)(PPh3)2 to give the stable ruthenium-substituted 1-azafulvene Ru(C[C4H3N]SCNMe2S)(η2-S2CNMe2)(CO)(PPh3) (A). Compound A can be protonated (reversibly) or methylated at the nitrogen of the 1-azafulvene to give compounds B and C respectively. The structure of B has been determined by a single crystal X-ray study. © 1990.

引用

页码：C9 / C12

页数：4

共 4 条

[1] ORGAN SYNTHESES WITH TRANSITION-METAL COMPLEXES .24. NITROGEN-HETEROCYCLES FROM CARBENE COMPLEXES AND ALKENYL ISOCYANIDES [J].