PHOTOCHEMISTRY OF A STRUCTURALLY UNCOMPLICATED PHENYLCARBYNE COMPLEX

被引：19

作者：

TRAMMELL, S

SULLIVAN, BP

HODGES, LM

HARMAN, WD

SMITH, SR

THORP, HH

机构：

[1] UNIV WYOMING,DEPT CHEM,LARAMIE,WY 82071

[2] UNIV VIRGINIA,DEPT CHEM,CHARLOTTESVILLE,VA 22901

[3] UNIV N CAROLINA,DEPT CHEM,CHAPEL HILL,NC 27599

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 11期

关键词：

D O I：

10.1021/ic00115a001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[Os(NH3)(5)CPh](O3SCF3)(3) is the first example of an Os carbyne that is luminescent in fluid solution. In CH3CN the complex exhibits a broad emission centered at 632 nm with a lifetime of 55 ns. Of note is a unique base-induced quenching process that occurs with substituted pyridines.

引用

收藏

页码：2791 / 2792

页数：2

相关论文

共 27 条

[1] THE REACTIONS OF AN AMBIDENT LITHIUM MOLYBDENUMVINYLIDENE COMPLEX WITH ELECTROPHILES - NOVEL FORMATION OF A 1,3-DIENE COMPLEX AND EVIDENCE FOR INTRAMOLECULAR CARBON-HYDROGEN ACTIVATION ON PHOTOLYSIS OF A CARBYNE COMPLEX [J].

BEEVOR, RG ;

FREEMAN, MJ ;

GREEN, M ;

MORTON, CE ;

ORPEN, AG .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (02) :68-70

[2] PHOTOEMISSION FROM TUNGSTEN ALKYLIDYNE COMPLEXES IN FLUID SOLUTION [J].

BOCARSLY, AB ;

CAMERON, RE ;

RUBIN, HD ;

MCDERMOTT, GA ;

WOLFF, CR ;

MAYR, A .

INORGANIC CHEMISTRY, 1985, 24 (24) :3976-3978

[3] MOLYBDENUM CARBYNE, VINYLIDENE, AND KETENYL COMPLEXES WITH HYDROTRIS(3,5-DIMETHYLPYRAZOLYL)BORATE LIGANDS [J].

BROWER, DC ;

STOLL, M ;

TEMPLETON, JL .

ORGANOMETALLICS, 1989, 8 (12) :2786-2792

[4] PHOTOOXIDATION OF THE MOLYBDENUM AND TUNGSTEN CARBYNES (ETA-5-C5H5)L2M=CR [L = P(OME)3, CO AND R = PH, ME, C-C3H5] [J].

CARTER, JD ;

KINGSBURY, KB ;

WILDE, A ;

SCHOCH, TK ;

LEEP, CJ ;

PHAM, EK ;

MCELWEEWHITE, L .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (08) :2947-2954

[5] METAL-NITRIDO PHOTO-OXIDANTS - SYNTHESIS, PHOTOPHYSICS, AND PHOTOCHEMISTRY OF [OSVI(NH3)4(N)] (X)3 (X = CL, CF3SO3) [J].

CHE, CM ;

LAU, TC ;

LAM, HW ;

POON, CK .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (02) :114-116

[6] METAL NITRIDO AND IMIDO PHOTO-OXIDANTS - PHOTOPHYSICS AND PHOTOCHEMISTRY OF NITRIDO AND IMIDO COMPLEXES OF OSMIUM(VI) AND X-RAY CRYSTAL-STRUCTURE OF [PH4AS]2[OSVI(CN)5N] [J].

CHE, CM ;

LAM, MHW ;

MAK, TCW .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (20) :1529-1531

[7]

CHE CM, 1993, INORG CHIM ACTA, V204, P133

[8]

CHE CM, 1992, J CHEM SOC DA, P1411

[9] DEAROMATIZATION OF FURAN - STRUCTURE OF AN ETA(2)-FURAN COMPLEX AND A SURVEY OF ITS REACTIVITY [J].

CHEN, HY ;

HODGES, LM ;

LIU, RG ;

STEVENS, WC ;

SABAT, M ;

HARMAN, WD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (12) :5499-5500

[10] ELECTRONIC-STRUCTURES AND SPECTRA OF NITRIDO COMPLEXES OF OSMIUM(VI) [J].

COWMAN, CD ;

TROGLER, WC ;

MANN, KR ;

POON, CK ;

GRAY, HB .

INORGANIC CHEMISTRY, 1976, 15 (08) :1747-1751