NEW BINUCLEATING AMIDO LIGANDS, SYNTHESIS AND STRUCTURES OF COPPER(II) AND MANGANESE(III) COMPLEXES

被引：15

作者：

BERTONCELLO, K ^{[1
]}

FALLON, GD ^{[1
]}

MURRAY, KS ^{[1
]}

机构：

[1] MONASH UNIV, DEPT CHEM, CLAYTON, VIC 3168, AUSTRALIA

来源：

POLYHEDRON | 1990年 / 9卷 / 23期

关键词：

D O I：

10.1016/S0277-5387(00)84192-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New binucleating ligands containing μ-alkoxo backbones and amido-pyridyl or amido-phenol "end" groups have been synthesized. The syntheses and structures of mononuclear CuII and binuclear (CuIICuII and MnIIIMnIII) complexes are described. The crystal structure of a novel doubly-bridged MnIIIMnIII complex shows that each six-coordinate manganese is bridged by endogenous μ-alkoxo and exogenous μ-acetato groups. Chemical or electrochemical oxidations will be required to obtain higher oxidation state metallo species. © 1990.

引用

页码：2867 / 2871

页数：5

共 23 条

[1] METAL-COMPLEXES OF THE DEPROTONATED FORM OF N,N'-BIS(2'-PYRIDINECARBOXAMIDE 1'-OXIDE)-1,2-ETHANE, (ENPCO), A DINEGATIVE N2O2 QUADRIDENTATE PYRIDINE N-OXIDE LIGAND - X-RAY CRYSTAL-STRUCTURE OF [CU(ENPCO-2H)]2.8H2O [J].

ANTOLOVICH, M ;

PHILLIPS, DJ ;

RAE, AD .

INORGANICA CHIMICA ACTA, 1989, 156 (02) :189-193

[2] STUDIES ON THE METAL-AMIDE BOND .7. METAL-COMPLEXES OF THE FLEXIBLE N4 LIGAND N,N'-BIS(2'-PYRIDINE-CARBOXAMIDE)1,2-ETHANE [J].

BARNES, DJ ;

CHAPMAN, RL ;

STEPHENS, FS ;

VAGG, RS .

INORGANICA CHIMICA ACTA-ARTICLES, 1981, 51 (02) :155-162

[3] SYNTHESIS AND STRUCTURE OF TETRADENTATE AMIDO-PHENOLATE MANGANESE(III) COMPLEXES - PRECURSORS FOR HIGH-VALENT MANGANESE CHELATE COMPLEXES [J].

BERTONCELLO, K ;

FALLON, GD ;

MURRAY, KS .

INORGANICA CHIMICA ACTA, 1990, 174 (01) :57-60

[4]

BRUDVIG GW, 1989, PROG INORG CHEM, V37, P99

[5] MANGANESE(IV) AMIDE BINDING - STRUCTURAL CHARACTERIZATION AND REDOX STABILITY OF A HEXADENTATE COMPLEX [J].

CHANDRA, SK ;

CHOUDHURY, SB ;

RAY, D ;

CHAKRAVORTY, A .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (06) :474-475

[6] STUDIES ON THE METAL-AMIDE BOND .2. THE CRYSTAL-STRUCTURE OF THE DEPROTONATED COPPER(II) COMPLEX OF N,N'-BIS-(2'-PYRIDINECARBOXAMIDE)-1,2-BENZENE [J].

CHAPMAN, RL ;

STEPHENS, FS ;

VAGG, RS .

INORGANICA CHIMICA ACTA-ARTICLES, 1980, 43 (01) :29-33

[7] MANGANESE CARBOXYLATE CHEMISTRY AND ITS BIOLOGICAL RELEVANCE [J].

CHRISTOU, G .

ACCOUNTS OF CHEMICAL RESEARCH, 1989, 22 (09) :328-335

[8] A MANGANESE(V)-OXO COMPLEX [J].

COLLINS, TJ ;

GORDONWYLIE, SW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (12) :4511-4513

[9]

Fenton D. E., 1983, ADV INORG BIOINORG, V2, P187

[10] BINUCLEAR COPPER(II) COMPLEXES OF NEW DINUCLEATING LIGANDS WITH A PYRAZOLATE GROUP AS AN ENDOGENOUS BRIDGE - EFFECTS OF EXOGENOUS AZIDE AND ACETATE BRIDGES ON MAGNETIC-PROPERTIES [J].

KAMIUSUKI, T ;

OKAWA, H ;

KITAURA, E ;

KOIKAWA, M ;

MATSUMOTO, N ;

KIDA, S ;

OSHIO, H .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (11) :2077-2081

← 1 2 3 →