AMIDINATO COMPLEXES OF THE PLATINUM METALS AND AN AVID CARBONYL ABSTRACTION REACTION

被引：4

作者：

CLARK, T ^{[1
]}

ROBINSON, SD ^{[1
]}

机构：

[1] UNIV LONDON KINGS COLL,DEPT CHEM,LONDON WC2R 2LS,ENGLAND

来源：

POLYHEDRON | 1992年 / 11卷 / 08期

关键词：

D O I：

10.1016/S0277-5387(00)83353-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Platinum metal hydrido and trifluoroacetato complexes react with N,N'-diphenylamidines, PhN = C(R)-NHPh (R = H, Me, Et, Ph), giving the amidinato derivatives Ru{PhNC(R)NPh}2(CO)(PPh3), MX{PhNC(R)NPh}(CO)(PPh3)2 and IrX2{PhNC(R) NPh}(PPh3)2 (M = Ru, Os; X = H, Cl; X2 = H-2, Cl2 or HCl). The reactions of RuH2(PPh3)4 and OsH4(PPh3)3 with amidines are accompanied by an avid alcohol decarbonylation reaction to form the carbonyls MH{PhNC(R)NPh}(CO)(PPh3)2.

引用

页码：993 / 994

页数：2

共 11 条

[1] COMPLEXES OF PLATINUM METALS .12. N,N'-DI-PARA-TOLYLFORMAMIDINATO DERIVATIVES OF RUTHENIUM, OSMIUM, AND IRIDIUM - CRYSTAL-STRUCTURE OF TRANS-BIS(TRIPHENYLPHOSPHINE)CARBONYL(N,N'-DI-PARA-TOLYLFORMAMIDINATO)-HYDRIDORUTHENIUM(II) [J].

BROWN, LD ;

ROBINSON, SD ;

SAHAJPAL, A ;

IBERS, JA .

INORGANIC CHEMISTRY, 1977, 16 (11) :2728-2735

[2] VANADIUM(II)-FORMAMIDINATO AND VANADIUM(III)-FORMAMIDINATO COMPOUNDS - SYNTHESIS AND MOLECULAR-STRUCTURE OF V(FORM)2(NC5H5)2 AND V(ETA-5-C5H5)(FORM)2 [FORM=N,N'-DI-PARA-TOLYLFORMAMIDINE] [J].

COTTON, FA ;

POLI, R .

INORGANICA CHIMICA ACTA, 1988, 141 (01) :91-98

[3]

COTTON FA, 1987, POLYHEDRON, V6, P1625

[4] SYNTHESIS, MOLECULAR-STRUCTURE, AND PHYSICOCHEMICAL PROPERTIES OF NI2(N,N'-DI-PARA-TOLYLFORMAMIDINATO)4, PD 2 (N,N'-DI-PARA-TOLYLFORMAMIDINATO)4 - ATTEMPTS TO GENERATE A PALLADIUM(III) DIMER [J].

COTTON, FA ;

MATUSZ, M ;

POLI, R .

INORGANIC CHEMISTRY, 1987, 26 (10) :1472-1474

[5] STRUCTURE OF DICARBONYL-ETA-CYCLOPENTADIENYL)(N,N'-DIPHENYLACETAMIDINATO)-MOLYBDENUM(II), [MO(C5H5)(C14H13N2)(CO)2] [J].

GAYLANI, B ;

KILNER, M ;

FRENCH, CI ;

PICK, AJ ;

WALLWORK, SC .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 :257-259

[6] COMPLEXES OF PLATINUM METALS .4. 1,3-DIARYLTRIAZENIDO DERIVATIVES [J].

LAING, KR ;

ROBINSON, SD ;

UTTLEY, MF .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1974, (11) :1205-1214

[7]

LAPIDO FT, 1990, INORG CHEM, V29, P4172

[8] SYNTHESIS AND CHARACTERIZATION OF DIRHODIUM COMPLEXES WITH 4 N,N'-DIPHENYLBENZAMIDINE BRIDGING LIGANDS - ELECTROCHEMICAL GENERATION AND ELECTRON-SPIN-RESONANCE PROPERTIES OF [RH2(N2R2CR)4]N WHERE R = PHENYL AND N = 1 AND -1 [J].

LE, JC ;

CHAVAN, MY ;

CHAU, LK ;

BEAR, JL ;

KADISH, KM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (24) :7195-7197

[9] SYNTHESIS, X-RAY CRYSTAL-STRUCTURE, AND ELECTROCHEMICAL PROPERTIES OF THE RH2(4+) COMPLEX RH2(N,N'-DI-PARA-TOLYLFORMAMIDINATE ANION)4 [J].

PIRAINO, P ;

BRUNO, G ;

LOSCHIAVO, S ;

LASCHI, F ;

ZANELLO, P .

INORGANIC CHEMISTRY, 1987, 26 (14) :2205-2211

[10] COMPLEXES OF PLATINUM METALS .2. CARBOXYLATO(TRIPHENYLPHOSPHINE) DERIVATIVES OF RUTHENIUM, OSMIUM, RHODIUM, AND IRIDIUM [J].

ROBINSON, SD ;

UTTLEY, MF .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1973, (18) :1912-1920

← 1 2 →