PRENYLATION OF AROMATICS - LITHIUM-AMMONIA REDUCTION OF O-SILYLATED TERTIARY CINNAMYL ALCOHOLS

被引：6

作者：

BALLESTER, P ^{[1
]}

CAPO, M ^{[1
]}

SAA, JM ^{[1
]}

机构：

[1] UNIV ILLES BALEARS,DEPT QUIM,E-07071 PALMA DE MALLORCA,SPAIN

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 09期

关键词：

D O I：

10.1016/S0040-4039(00)88801-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Silyl protected phenolic or non-phenolic tertiary cinnamyl alcohols undergo metalammonia induced hydrogenolysis with concomitant double bond isomerization, thus providing a unique entrance to prenyl substituted aromatics. Chiral alcohols yielded E:Z mixtures enriched (2.5:1) in the E isomer. © 1990.

引用

页码：1339 / 1342

页数：4

共 21 条

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