TEMPERATURE-DEPENDENCE OF N+N-2 RATE COEFFICIENTS

被引：74

作者：

LAGANA, A ^{[1
]}

GARCIA, E ^{[1
]}

机构：

[1] UNIV BASQUE COUNTRY, DEPT QUIM FIS, E-48080 BILBAO, SPAIN

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1994年 / 98卷 / 02期

关键词：

D O I：

10.1021/j100053a025

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

After the validity of two model potential energy surfaces was tested, quasiclassical calculations of vibrational deexcitation rate coefficients for the nitrogen-atom nitrogen-molecule reaction were performed for a range of reactant vibrational numbers extending up to v = 45 and a set of translational and rotational temperatures ranging from 500 to 4000 K. The different effect of varying either the rotational or the translational temperature on the relative efficiency of reactive and nonreactive vibrational transitions is discussed in detail.

引用

页码：502 / 507

页数：6

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