A BROAD LINE NMR-STUDY OF ORIENTED POLY(VINYLIDENE FLUORIDE)

被引：17

作者：

CLEMENTS, J

DAVIES, GR

WARD, IM

机构：

[1] Univ of Leeds, Dep of Physics,, Leeds, Engl, Univ of Leeds, Dep of Physics, Leeds, Engl

来源：

POLYMER | 1985年 / 26卷 / 02期

关键词：

MAGNETIC MEASUREMENTS - Resonance - MAGNETIC RESONANCE;

D O I：

10.1016/0032-3861(85)90032-1

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Broadline nuclear magnetic resonance measurements have been carried out for the proton resonance in oriented poly(vinylidene fluoride). The spectra in general show two component lines with distinctly different line widths. The broad component shows a high degree of molecular orientation and can be satisfactorily assigned to the crystalline regions of the polymer. The narrow component corresponds to an oriented non crystalline phase which is sufficiently constrained to allow motion about the chain axis only. An appreciable decrease in the value of the rigid mass fraction was observed in both of the samples over the temperature range examined.

引用

页码：208 / 218

页数：11

共 22 条

[1] NUCLEAR MAGNETIC RESONANCE MODULATION CORRECTION [J].