REDOX-CONTROLLED CHEMICAL SWITCHING OF CATION-TRANSPORT IN SOLID-SUPPORTED MEMBRANE SYSTEMS

被引：23

作者：

CHEN, ZH ^{[1
]}

GOKEL, GW ^{[1
]}

ECHEGOYEN, L ^{[1
]}

机构：

[1] UNIV MIAMI,DEPT CHEM,CORAL GABLES,FL 33124

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1991年 / 56卷 / 10期

关键词：

D O I：

10.1021/jo00010a035

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Redox-switchable anthraquinone-substituted crown ethers may be reduced by treatment with NaBH4 to afford high-binding, water-stable, anion derivatives. These macrocycles, including 1-((9,10-dioxo-1-oxanthracenyl)-methyl-15-crown-5, 1, transport Na+ through a solid-supported, o-nitrophenyl octyl ether membrane with rates that depend on the charge state of the ligand and cooperation between reduction at the source phase and oxidation at the receiving phase.

引用

页码：3369 / 3372

页数：4

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