POSSIBLE STRUCTURE OF PARATHIOCYANOGEN - AN IR AND UV STUDY

被引：21

作者：

CATALDO, F

机构：

[1] PROGEGA s.n.c., Rome, 00128

来源：

POLYHEDRON | 1992年 / 11卷 / 01期

关键词：

D O I：

10.1016/S0277-5387(00)83263-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Parathiocyanogen or polythiocyanogen (SCN)x has been prepared by the action of chlorine over solid NaSCN. It is shown by comparing the IR and UV spectra of parathiocyanogen with those of NaSCN, Na(SCN)3 and a triazine-based model compound that (SCN)x has not a triazine-based structure. A linear structure similar to that assigned to polysulphur nitride is proposed.

引用

页码：79 / 83

页数：5

共 18 条

[1] BHATNAGAR SS, 1940, J INDIAN CHEM SOC, V17, P529
[2] PARACYANOGEN - ITS FORMATION AND PROPERTIES .1.
BIRCUMSHAW, LL
TAYLER, FM
WHIFFEN, DH
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1954, (MAR): : 931 - &
[3] THERMALLY AND PHOTOCHEMICALLY INITIATED POLYMERIZATION PROCESSES IN THE SOLID-STATE
BURDETT, JK
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (17) : 5458 - 5462
[4] CATALDO F, UNPUB
[5] CATALDO F, Patent No. 4809989
[6] SPECTRA + SEMI-CONDUCTIVITY OF (SN)X POLYMER
CHAPMAN, D
YOFFE, AD
FITZGERALD, AG
WARN, RJ
[J]. TRANSACTIONS OF THE FARADAY SOCIETY, 1964, 60 (4942): : 294 - &
[7] SOLID-STATE POLYMERIZATION OF S2N2 TO (SN)X
COHEN, MJ
GARITO, AF
HEEGER, AJ
MACDIARMID, AG
MIKULSKI, CM
SARAN, MS
KLEPPINGER, J
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (13) : 3844 - 3848
[8] BEITRAGE ZUR CHEMIE DES SCHWEFELS .57. DIE POLYMERISATION DER CYANSULFANE
FEHER, F
LINKE, KH
HIRSCHFE.D
[J]. ZEITSCHRIFT FUR NATURFORSCHUNG PART B-CHEMIE BIOCHEMIE BIOPHYSIK BIOLOGIE UND VERWANDTEN GEBIETE, 1962, B 17 (09): : 624 - &
[9] FEHER F, 1958, CHEM BER, V91, P624
[10] KERSTEIN H, 1924, CHEM BER, V57, P491

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