HOMOALLYL CYANIDE AND N-ALLYLKETENE IMINE - A [3,3]SIGMATROPIC EQUILIBRIUM

被引：4

作者：

BRUCKNER, R ^{[1
]}

HUISGEN, R ^{[1
]}

机构：

[1] UNIV MUNICH,INST ORGAN CHEM,D-80333 MUNICH,GERMANY

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 20期

关键词：

D O I：

10.1016/S0040-4039(00)76885-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The [sic],delta-unsaturated nitrile 2 equilibrates at room temperature with the N-allylketene imine 3. Deuterium labeling established an intramolecular rearrangement, and the small influence of solvent polarity on the rare constants is in accordance with a concerted [3,3]sigmatropic shift.

引用

页码：3281 / 3284

页数：4

共 12 条

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