A STABLE PALLADIUM(I) DIMER WITH ONE 14E PALLADIUM CENTER AND ITS REVERSIBLE-REACTION WITH CS2, AFFORDING A NEW COMPLEX WITH A PLANAR 4-COORDINATE CARBON

被引：26

作者：

LEONI, P

PASQUALI, M

PIERI, G

ALBINATI, A

PREGOSIN, PS

RUEGGER, H

机构：

[1] UNIV PISA,DIPARTIMENTO CHIM & CHIM IND,I-56126 PISA,ITALY

[2] UNIV MILAN,IST CHIM FARMACEUT,I-20131 MILAN,ITALY

[3] ETH ZENTRUM,ANORGAN CHEM LAB,CH-8092 ZURICH,SWITZERLAND

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 07期

关键词：

D O I：

10.1021/om00007a009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

True new stable dinuclear Pd(I) complexes, [Pd-2(mu-PBu(t)2),(PPh(3))(3)]X and [Pd-2(mu-PBu(2)(t))(PPh(3))(2)(mu,eta(2): eta(2)-CS2)]X(X = BF4, CF3SO3), have been synthesized and characterized. The former has one 14e Pd center, and the latter, which has been characterized by X-ray diffraction, contains a CS2 molecule with a four-coordinate planar CS2 carbon.

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页码：3143 / 3145

页数：3

相关论文

共 14 条

[1] PD-H-P BRIDGING IN A PALLADIUM(I) DIMER [J].

ALBINATI, A ;

LIANZA, F ;

PASQUALI, M ;

SOMMOVIGO, M ;

LEONI, P ;

PREGOSIN, PS ;

RUEGGER, H .

INORGANIC CHEMISTRY, 1991, 30 (25) :4690-4692

[2] METALLORGANIC LEWIS-ACIDS .26. EVIDENCE OF DYNAMIC BEHAVIOR OF COORDINATED TETRAFLUOROBORATE LIGANDS IN CP(OC)2(R3P) USING F-19 NMR-SPECTROSCOPY [J].

APPEL, M ;

BECK, W .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 319 (01) :C1-C4

[3] COMPARISON OF DIFFERENT 2D-NMR TECHNIQUES FOR C-13, P-31 CORRELATION [J].

BAST, P ;

BERGER, S ;

GUNTHER, H .

MAGNETIC RESONANCE IN CHEMISTRY, 1992, 30 (07) :587-594

[4] METAL-COMPLEXES OF WEAKLY COORDINATING ANIONS - PRECURSORS OF STRONG CATIONIC ORGANOMETALLIC LEWIS-ACIDS [J].

BECK, W ;

SUNKEL, K .

CHEMICAL REVIEWS, 1988, 88 (07) :1405-1421

[5] A DOUBLE CS2-BRIDGED NICKEL-COMPLEX - NEW SYNTHESIS AND CRYSTAL-STRUCTURE OF [(PPH3)NI(MU-CS2)2NI(PPH3)] [J].

BIANCHINI, C ;

GHILARDI, CA ;

MELI, A ;

MIDOLLINI, S ;

ORLANDINI, A .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (13) :753-754

[6] ALLENE ADDUCTS OF DITUNGSTEN HEXAALKOXIDES - 3 MODES OF ALLENE COORDINATION TO DINUCLEAR CENTERS AS SEEN IN THE STRUCTURES OF W2(O-TERT-BU)6(C3H4), W2(O-TERT-BU)6(C3H4)2, AND W2(O-TERT-BU)6(C3H4)(CO)2 [J].

CHACON, ST ;

CHISHOLM, MH ;

FOLTING, K ;

HUFFMAN, JC ;

HAMPDENSMITH, MJ .

ORGANOMETALLICS, 1991, 10 (10) :3722-3735

[7] ADDITION OF DI-PARA-TOLYLCARBODIIMIDE TO DITUNGSTEN HEXA-TERT-BUTOXIDE - PREPARATION AND STRUCTURE OF [W(OCME3)3]2(MU-C7H7NCNC7H7) [J].

COTTON, FA ;

SCHWOTZER, W ;

SHAMSHOUM, ES .

ORGANOMETALLICS, 1985, 4 (03) :461-465

[8]

ERKER G, 1993, ANGEW CHEM, V105, P1691

[9] REACTIONS OF CARBON-DISULFIDE WITH PALLADIUM(0) COMPLEXES [J].

FARRAR, DH ;

GUKATHASAN, RR ;

WON, K .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1984, 275 (02) :263-271

[10] REACTION OF CS2 WITH TRINUCLEAR PD AND PT CLUSTERS - CRYSTAL-STRUCTURE OF PT2(MU-CS2)2(P(TERT-BU)2PH)2 [J].

FARRAR, DH ;

GUKATHASAN, RR ;

MORRIS, SA .

INORGANIC CHEMISTRY, 1984, 23 (20) :3258-3261