BISMUTH LEAD-OXIDE, A NEW HIGHLY CONDUCTIVE OXYGEN MATERIAL

被引：42

作者：

HONNART, F ^{[1
]}

BOIVIN, JC ^{[1
]}

THOMAS, D ^{[1
]}

DEVRIES, KJ ^{[1
]}

机构：

[1] TWENTE UNIV TECHNOL,DEPT CHEM ENGN,INORGAN MAT SCI LAB,7500 AE ENSCHEDE,NETHERLANDS

来源：

SOLID STATE IONICS | 1983年 / 9-10卷 / DEC期

关键词：

BISMUTH COMPOUNDS - Electric Conductivity - CRYSTALS - Structure - IONS - Transport Properties - LEAD COMPOUNDS - Electric Conductivity;

D O I：

10.1016/0167-2738(83)90111-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The transport properties of an oxygen-deficient solid solution containing lead and bismuth oxides have been investigated. The conductivity is larger than 1( OMEGA x cm)** minus **1 at 600 degree C. Thermogalvanic measurements confirm that no significant electronic contribution occurs in the range 1-10** minus **3 atm p O//2. The heat of transport of O**2** minus ions is calculated and is in agreement with the activation energy of conduction.

引用

页码：921 / 924

页数：4

共 16 条

[1] BARIN I, 1973, ISBN354060537
[2] BOIVIN J, UNPUB
[3] BOIVIN JC, 1975, THESIS LILLE
[4] STRUCTURE AND CONDUCTIVITY OF PYROCHLORE AND FLUORITE TYPE SOLID-SOLUTIONS
BURGGRAAF, AJ
VANDIJK, T
VERKERK, MJ
[J]. SOLID STATE IONICS, 1981, 5 (OCT) : 519 - 522
[5] CUSACK M, 1958, P PHYS SOC LONDON A, V72, P8
[6] DEMONCHY P, 1980, CR ACAD SCI C CHIM, V290, P279
[7] DEMONCHY P, 1979, CR ACAD SCI C CHIM, V289, P317
[8] DEMONCHY P, 1981, THESIS LILLE
[9] ELECTRICAL-PROPERTIES OF ALPHA, BETA, GAMMA AND DELTA PHASES OF BISMUTH SESQUIOXIDE
HARWIG, HA
GERARDS, AG
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 1978, 26 (03) : 265 - 274
[10] THE THERMOELECTRIC-POWER IN BI2O3
HONDERS, A
DEWIT, JHW
[J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 1980, 10 (03) : 409 - 414

← 1 2 →