SCHIFF-BASES AS ADDED CHIRAL LIGANDS FOR THE [RU(ETA(6)-C6H6)CL2](2) CATALYZED HYDROGEN-TRANSFER REDUCTION OF KETONES WITH 2-PROPANOL

被引：65

作者：

KRASIK, P ^{[1
]}

ALPER, H ^{[1
]}

机构：

[1] UNIV OTTAWA,OTTAWA CARLETON CHEM INST,DEPT CHEM,OTTAWA K1N 6N5,ON,CANADA

来源：

TETRAHEDRON | 1994年 / 50卷 / 15期

关键词：

D O I：

10.1016/S0040-4020(01)89371-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ruthenium complexes generated in situ from [Ru(C6H6)Cl-2](2) and chiral Schiff bases [derived from(1R,2R)-diaminocyclohexane] catalyse asymmetric hydrogen-transfer reduction of alkyl aryl ketones by 2-propanol to give the (S)-alcohol in up to 40% ee.

引用

页码：4347 / 4354

页数：8

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