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SYNTHESIS OF ACYL(PHENYLSELANYL)METHYLIDENE(TRIPHENYL)-LAMBDA(5)-ARSANES AND THEIR WITTIG-TYPE REACTIONS

被引：31
作者：
HUANG, ZZ
HUANG, X
HUANG, YZ
机构：
[1] HANGZHOU UNIV,DEPT CHEM,HANGZHOU 310028,PEOPLES R CHINA
[2] ACAD SINICA,SHANGHAI INST ORGAN CHEM,SHANGHAI 200032,PEOPLES R CHINA
来源：
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1995年 / 02期
关键词：
D O I：
10.1039/p19950000095
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Acyl(phenylselanyl)methylidene(triphenyl)-lambda(5)-arsanes 3 have been synthesized by treating acylmethylidene(triphenyl)-lambda(5)-arsanes 1 with phenylselanyl iodide 2; alpha-selanylarsonium ylides 3 are sufficiently reactive to undergo Wittig-type reactions, affording a novel method for the stereoselective synthesis of (Z)-alpha-phenylselanyl alpha,beta-unsaturated ketones 6.
引用
收藏
页码：95 / 96
页数：2
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