LOW-TEMPERATURE CALORIMETRY FOR WEAKLY INTERACTING MOLECULAR-SYSTEMS

被引：11

作者：

MATSUO, T ^{[1
]}

机构：

[1] OSAKA UNIV,FAC SCI,MICROCALORIMETRY RES CTR,TOYONAKA,OSAKA 560,JAPAN

来源：

PURE AND APPLIED CHEMISTRY | 1995年 / 67卷 / 06期

关键词：

D O I：

10.1351/pac199567060911

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

With development of small-sample calorimeters and their computer control, adiabatic low temperature calorimetry, an established source of chemical thermodynamic properties, has now become one of the diverse experimental methods for studying more general low temperature properties of matter. A device to increase the efficiency of the calorimetric experiment is described. Calorimetric studies of deuterium-induced phase transitions for which recent development of the experimental technique was essential are reviewed. Substances discussed are ammonium hexachlorometallates, rubidium hydrogen selenate, 5-bromo-9-hydroxyphenalenone and their deuterated analogues.

引用

页码：911 / 918

页数：8

共 45 条

[1] GIANT METAL-INSULATOR METAL TRANSITION INDUCED BY SELECTIVE DEUTERATION OF THE MOLECULAR CONDUCTOR, (DME-DCNQI)2CU (DME-DCNQI=2,5-DIMETHYL-N,N'-DICYANOQUINONEDIIMINE) [J].

AONUMA, S ;

SAWA, H ;

KATO, R ;

KOBAYASHI, H .

CHEMISTRY LETTERS, 1993, (03) :513-516

[2] NEUTRON-DIFFRACTION STUDY OF THE ORTHORHOMBIC LOW-TEMPERATURE PHASE OF N2D7I AND X-RAY-INVESTIGATIONS OF THE TETRAGONAL AND ORTHORHOMBIC PHASES OF N2H7I [J].

BERTHOLD, HJ ;

VONHOLDT, E ;

WARTCHOW, R ;

VOGT, T .

ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1993, 203 :199-214

[3] CALORIMETRIC STUDIES OF THE PHASE-TRANSITION IN IODOFORM [J].

BOERIOGOATES, J ;

WOODFIELD, BF .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1988, 66 (04) :645-650

[4] HEAT-CAPACITIES OF DIHYDROGEN AND DIDEUTERIUM THALLIUM (1) ORTHO-PHOSPHATES - THERMODYNAMIC PROPERTIES OF SOLID-PHASE TRANSITIONS [J].

BOUSQUET, J ;

DIOT, M ;

TRANQUARD, A ;

COFFY, G ;

VIGNALOU, JR .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1978, 10 (08) :779-786

[5] THERMODYNAMICS OF AMMONIUM HALOGENATED TELLURIDES .2. HEAT-CAPACITY, PHASE-TRANSITIONS, AND THERMODYNAMIC PROPERTIES OF (ND4)2TECL6 AT TEMPERATURES FROM 5-K TO 325-K [J].

CALLANAN, JE ;

WEIR, RD ;

WESTRUM, EF .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1992, 24 (06) :661-672

[6] THERMODYNAMICS OF AMMONIUM HALOPALLIDATES .2. HEAT-CAPACITY AND THERMODYNAMIC PROPERTIES OF (ND4)2PDCL6 AT TEMPERATURES FROM 5-K TO 325-K [J].

CALLANAN, JE ;

WEIR, RD ;

WESTRUM, EF .

BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1992, 96 (11) :1585-1591

[7] THERMODYNAMICS OF AMMONIUM HALOGENATED TELLURIDES .1. HEAT-CAPACITY AND THERMODYNAMIC PROPERTIES OF (NH4)2TECL6 AT TEMPERATURES FROM 5-K TO 350-K [J].

CALLANAN, JE ;

WEIR, RD ;

WESTRUM, EF .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1992, 24 (06) :567-575

[8] THERMODYNAMIC PROPERTIES OF SOLID HYDROGEN HALIDES AND DEUTERIUM HALIDES .2. HBR AND DBR [J].

CHIHARA, H ;

INABA, A .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1976, 8 (10) :935-958

[9] D-2 NMR AND CL-35 NUCLEAR-QUADRUPOLE-RESONANCE STUDY OF AMMONIUM-ION MOTION AND PHASE-TRANSITIONS IN NATURAL AND DEUTERATED (NH4)2TECL6 [J].

DIMITROPOULOS, C ;

PELZL, J ;

BORSA, F .

PHYSICAL REVIEW B, 1990, 41 (07) :3914-3919

[10] PROTON-TRANSFER DYNAMICS IN THE HYDROGEN-BOND - INELASTIC NEUTRON-SCATTERING, INFRARED AND RAMAN-SPECTRA OF NA3H(SO4)2, K3H(SO4)2 AND RB3H(SO4)2 [J].

FILLAUX, F ;

LAUTIE, A ;

TOMKINSON, J ;

KEARLEY, GJ .

CHEMICAL PHYSICS, 1991, 154 (01) :135-144

← 1 2 3 4 5 →