Anomaly in magnetic properties of poly(3-alkylthiophene)s depending on alkyl chain length

被引：28

作者：

Cik, G

Sersen, F

Dlhan, L

Szabo, L

Bartus, J

机构：

[1] COMENIUS UNIV BRATISLAVA, FAC NAT SCI, INST CHEM, BRATISLAVA 84215, SLOVAKIA

[2] SLOVAK UNIV TECHNOL BRATISLAVA, DEPT INORGAN CHEM, BRATISLAVA 81237, SLOVAKIA

[3] NASHUA CORP, MERRIMACK, NH 03054 USA

来源：

SYNTHETIC METALS | 1995年 / 75卷 / 01期

关键词：

magnetic properties; poly(3-alkylthiophene); antiferromagnetism;

D O I：

10.1016/0379-6779(95)03381-S

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The influence of the alkyl side-chain length exerted on the magnetic properties of poly(3-alkylthiophene)s, i.e. poly(3-dodecylthiophene) (PDDT) and poly(3-hexadecylthiophene) (PHDT), has been studied. The temperature dependences of the magnetic susceptibility and EPR signal have shown that PDDT displays some antiferromagnetic properties at the Neel temperature of 237 K. However, these properties were unnoticed for PHDT. The anomaly in the magnetic properties of PDDT and PHDT is discussed within the scope of differences in the crystalline phase of polymer derivatives brought about by a different alkyl side-chain length.

引用

页码：43 / 48

页数：6

共 27 条

[1] STIFF-CHAIN POLYMERS - STRUCTURE, PHASE-BEHAVIOR, AND PROPERTIES [J].