SYNERGISTIC SOLVENT-EXTRACTION OF AM(III) AND EU(III) WITH THE SOFT DONOR TRIISOBUTYLPHOSPHINE SULFIDE AND THENOYLTRIFLUOROACETONE

被引：10

作者：

WHARF, RM ^{[1
]}

CHOPPIN, GR ^{[1
]}

PRUETT, DJ ^{[1
]}

机构：

[1] OAK RIDGE NATL LAB,OAK RIDGE,TN 37831

来源：

SOLVENT EXTRACTION AND ION EXCHANGE | 1990年 / 8卷 / 4-5期

关键词：

D O I：

10.1080/07366299008918020

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synergistic solvent extraction of Am(III) and Eu(III) with the neutral soft donor TIBPS and HTTA has been investigated using cyclohexane as the organic solvent and at an ionic strength of 0.1 M (NaCIO,). The extracted species are [M(TTA)3)] and [M(TTA)2(C1O4) (TIBPS) ]. The extraction constants show that the synergistic factor is less than that for the analogous hard donor adducts (e.g., TBP and TOPO) and no preferential extraction of Am(III) over Eu(III) is observed. © 1990, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：615 / 627

页数：13

共 14 条

[1] EFFECT OF DILUENT ON SYNERGIC EXTRACTION OF EUROPIUM BY THENOYLTRIFLUOROACETONE AND TRI-N-OCTYL PHOSPHINE OXIDE [J].

AKIBA, K ;

WADA, M ;

KANNO, T .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1981, 43 (05) :1031-1034

[2] TEMPERATURE EFFECT ON THE SYNERGIC EXTRACTION OF EUROPIUM BY THENOYLTRIFLUOROACETONE IN THE PRESENCE OF HETEROCYCLIC BIDENTATE AMINES FROM ACETATE BUFFER SOLUTIONS [J].

BHATTI, MS .

JOURNAL OF RADIOANALYTICAL CHEMISTRY, 1980, 57 (01) :69-78

[3] THE THERMODYNAMICS OF COMPLEXING OF LN(III) AND AM(III) BY CHLOROACETATES [J].

ENSOR, DD ;

CHOPPIN, GR .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1980, 42 (10) :1477-1480

[4] URANIUM(VI) AND RUTHENIUM EXTRACTION BY DIALKYLDITHIO-PHOSPHORIC ACIDS [J].

FITOUSSI, R ;

MUSIKAS, C .

SEPARATION SCIENCE AND TECHNOLOGY, 1980, 15 (04) :845-860

[5] SYNERGIC EFFECTS IN THE SOLVENT EXTRACTION OF THE ACTINIDES .4. TRIVALENT PLUTONIUM, AMERICIUM AND EUROPIUM [J].

IRVING, H ;

EDGINGTON, DN .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1961, 21 (1-2) :169-180

[6] SYNERGISTIC EXTRACTION OF TRIVALENT ACTINIDES BY MIXTURES OF THENOYLTRIFLUOROACETONE AND NEUTRAL OXO DONORS [J].

KHOPKAR, PK ;

MATHUR, JN .

SEPARATION SCIENCE AND TECHNOLOGY, 1981, 16 (08) :957-969

[7] SOLVENT-EXTRACTION OF DIOXOURANIUM(VI) WITH DIALKYLPHOSPHORODITHIOIC ACIDS .1. MECHANISM OF EXTRACTION IN NORMAL-BUTANOL [J].

MARCU, G ;

CURTUI, M ;

HAIDUC, I .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1977, 39 (08) :1415-1418

[8]

Mathur J. N., 1983, SOLVENT EXTR ION EXC, V1, P349, DOI DOI 10.1080/07366298308918406

[9]

MUSIKAS C, 1984, P INT S ACTINIDE LAN, P19

[10] THE PREPARATION AND CRYSTAL-STRUCTURES OF [LA(S2PET2)4][PH4AS], [ER(S2PET2)4][PH4AS] [J].

PINKERTON, AA ;

SCHWARZENBACH, D ;

SPILIADIS, S .

INORGANICA CHIMICA ACTA, 1987, 128 (02) :283-287

← 1 2 →