RUTHENIUM COMPLEX-CATALYZED SELECTIVE SYNTHESES OF 3,5-DIENOIC ACID-DERIVATIVES BY COUPLING OF 1,3-DIENES OR ALLYLIC CARBONATES WITH ACRYLIC COMPOUNDS

被引：51

作者：

MITSUDO, T

ZHANG, SW

KONDO, T

WATANABE, Y

机构：

[1] Department of Hydrocarbon Chemistry, Faculty of Engineering, Kyoto University, Sakyo-ku, Kyoto

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 03期

关键词：

1,3-DIENE; ALLYLIC CARBONATE; PI-ALLYLRUTHENIUM; 3,5-DIENOIC ACID DERIVATIVES;

D O I：

10.1016/S0040-4039(00)74126-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ru(cod)(cot) catalyzes highly selective codimerization of 1,3-dienes with acrylic compounds and first linear coupling reaction of allylic carbonates with the acrylic amide to give 3,5-dienoic acid derivatives; cod = cycloocta-1,5-diene, cot = cycloocta-1,3,5-triene.

引用

页码：341 / 344

页数：4

共 14 条

[1]

BOENNEMANN H, 1973, ANGEW CHEM INT EDIT, V12, P964

[2]

DZHEMILEV UM, 1978, ZH ORG KHIM+, V14, P225

[3] COBALT MEDIATED ALKENE DIENE COUPLING - DOCUMENTATION OF SCOPE, LIMITATIONS, AND REGIOSELECTIVITY [J].