SYNTHESIS AND ABSOLUTE-CONFIGURATION OF A CYTOTOXIC FATTY-ACID ISOLATED FROM THE MUSHROOM, HERICIUM-ERINACEUM

被引:22
作者
KUWAHARA, S
MORIHIRO, E
NEMOTO, A
HIRAMATSU, A
机构
[1] Laboratory of Agricultural Chemicals, Faculty of Agriculture, Ibaraki University, Ibaraki 300-03, Ami-machi, Inashihi-gun
关键词
D O I
10.1271/bbb.56.1417
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The naturally occurring (-)-enantiomer of a fatty acid isolated from the mushroom (Hericium erinaceum) was synthesized from (R)-(-)-benzyl glycidyl ether in 8 steps. A comparison of the specific rotation of the synthetic sample with that of the natural compound established the absolute configuration of the latter.
引用
收藏
页码:1417 / 1419
页数:3
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