SYNTHESIS OF ISOMERIC ETHYL TOLYLCYANOACETATES USING ORGANOIRON COMPLEXES

被引：11

作者：

ABDELAZIZ, AS

DEDENUS, CR

机构：

[1] Department of Chemistry, University of Winnipeg, Winnipeg, Manitoba

来源：

SYNTHETIC COMMUNICATIONS | 1992年 / 22卷 / 04期

关键词：

D O I：

10.1080/00397919208019257

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Nucleophilic aromatic substitution of isomeric chlorotoluenes complexed to the cyclopentadienyliron moiety with ethyl cyanoacetate in the presence of K2CO3 in DMF results in the formation of the isomeric ethyl tolylcyanoacetate complexes. Photolysis of these complexes leads to the formation of the title compounds in high yields.

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页码：581 / 591

页数：11

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