ZINC-COMPLEXES OF THE LIGAND TRIS(METHYLAMINOMETHYL)ETHANE

被引：22

作者：

BRANDT, W ^{[1
]}

WIRBSER, J ^{[1
]}

POWELL, AK ^{[1
]}

VAHRENKAMP, H ^{[1
]}

机构：

[1] UNIV FREIBURG,INST ANORGAN & ANALYT CHEM,ALBERSTR 21,W-7800 FREIBURG,GERMANY

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1991年 / 46卷 / 04期

关键词：

D O I：

10.1515/znb-1991-0404

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title ligand CH3C(CH2-NHCH3)3 was used to prepare complexes with zinc salts. In addition to the known 1:1 complexes of ZnCl2 and ZnBr2, those of ZnI2, Zn(SCN)2, Zn(CH3COO)2, and Zn(NO3)2, and the bis-ligand complex of Zn(ClO4)2 were obtained and characterized. Crystal structure determinations revealed a tetrahedral coordination with two nitrogen atoms of the ligand and two anions bound to zinc for the acetate complex and for the thiocyanate complex, upon crystallization of which the ligand was converted to an acetone aminal. In the bis-ligand zinc perchlorate complex the ligand is tridentate, and zinc has an octahedral coordination.

引用

页码：440 / 448

页数：9

共 22 条

[1] FUNCTIONAL TETRAHEDRAL ZINC-COMPLEXES [J].

ALSFASSER, R ;

POWELL, AK ;

VAHRENKAMP, H .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (08) :898-899

[2]

ALSFASSER R, 1990, ANGEW CHEM, V102, P939

[3]

[Anonymous], 1978, INFRARED RAMAN SPECT

[4]

[Anonymous], 1979, ADV INORG CHEM

[5]

BAILAR JC, 1969, J AM CHEM SOC, V91, P3212

[6] POLYNUCLEAR ZINC(II) COMPLEXES WITH LARGE POLYAZACYCLOALKANES - EQUILIBRIUM STUDIES AND CRYSTAL-STRUCTURE OF THE BINUCLEAR [ZN2([30]ANEN10)(NCS)](CLO4)3 COMPLEX [J].

BENCINI, A ;

BIANCHI, A ;

GARCIAESPANA, E ;

MANGANI, S ;

MICHELONI, M ;

ORIOLI, P ;

PAOLETTI, P .

INORGANIC CHEMISTRY, 1988, 27 (06) :1104-1107

[7]

BRODERSEN K, 1985, Z NATURFORSCH B, V40, P347

[8]

BROWN RS, 1983, MET IONS BIOL SYST, V15, P55

[9] ANIONIC FE3P CLUSTERS - PREPARATION AND REACTIONS INVOLVING FRAMEWORK CHANGES [J].

DECK, W ;

SCHWARZ, M ;

VAHRENKAMP, H .

CHEMISCHE BERICHTE-RECUEIL, 1987, 120 (09) :1515-1521

[10]

DUNN MF, 1975, STRUCT BONDING BERLI, V23, P61

← 1 2 3 →