ALKYNE COMPLEXES OF TITANOCENE AND PERMETHYLTITANOCENE WITHOUT ADDITIONAL LIGANDS - PRELIMINARY STRUCTURAL COMPARISONS

被引：47

作者：

ROSENTHAL, U

GORLS, H

BURLAKOV, VV

SHUR, VB

VOLPIN, ME

机构：

[1] UNIV JENA,MAX PLANCK GESELL,O-6900 JENA,GERMANY

[2] AKAD WISSENSCH USSR,INST ELEMENTORGAN VERBINDUNGEN,MOSCOW 117813,USSR

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 426卷 / 03期

关键词：

D O I：

10.1016/0022-328X(92)83073-Q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first complex of titanocene with an alkyne, Cp2Ti(Ph-C2-SiMe3), having no additional ligands, was structurally characterized and compared with the permethyltitanocene analogue Cp2*Ti(Ph-C2-SiMe3) to examine the different influences of Cp2Ti and Cp2*Ti on alkyne complexation.

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页码：C53 / C57

页数：5

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