SYNTHESIS OF AMINES VIA CARBON-SULFUR BOND CLEAVAGES OF SUBSTITUTED AMINOMETHYL SULFIDES WITH ORGANOLITHIUM REAGENTS - AMINOCARBENE ROUTE TO ENAMINES AND STERICALLY HINDERED AMINES

被引：13

作者：

EISCH, JJ

MCNULTY, JF

SHI, X

机构：

[1] Department of Chemistry, State University of New York, Binghamton

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 01期

关键词：

D O I：

10.1021/jo00080a003

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

N-Substituted and N,N-disubstituted aminomethyl sulfides can be converted into secondary and tertiary amines, respectively, by organolithium reagents in high yields, regardless of whether the N-substituent is alkyl or aryl; for the former case, imines, and for the latter case, aminocarbenes, are the most likely intermediates. © 1994, American Chemical Society. All rights reserved.

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页码：7 / 9

页数：3

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