FOURIER-TRANSFORM INFRARED STUDY OF TRICARBON HYDRIDE RADICALS TRAPPED IN AR AT 10-K

被引：99

作者：

HUANG, JW

GRAHAM, WRM

机构：

[1] Department of Physics, Texas Christian University, Fort Worth

来源：

JOURNAL OF CHEMICAL PHYSICS | 1990年 / 93卷 / 03期

关键词：

D O I：

10.1063/1.459137

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The vibrational spectra of tricarbon hydride radicals formed by trapping the products of the vacuum ultraviolet photolysis of methylacetylene and various deuterated isotopomers in argon at 10 K have been investigated by Fourier transform spectroscopy in the range 200-3400 cm-1. Supplementary studies have examined the photolysis products of allene as well as C 3H6 and C3D6, cyclopropane. The results reveal new information on the vibrations of C3H; five C 3H2 isomers, cyclopropenylidene, vinylidenecarbene, triplet propargylene, trans- and cis-propenediylidene; two C3H 3 isomers, propargyl and cyclopropenyl; and C3H 5, allyl. © 1990 American Institute of Physics.

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页码：1583 / 1596

页数：14

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