THE SYNTHESIS, MOLECULAR-STRUCTURE AND INTERCONVERSION OF 2 NOVEL BENZENE-COORDINATED PENTARUTHENIUM CARBIDO CLUSTER ISOMERS [RU5C(CO)12(MU-3-ETA-2-ETA-2-ETA-2-C6H6)] AND [RU5C(CO)12(ETA-6-C6H6)]

被引：31

作者：

BAILEY, PJ

BRAGA, D

DYSON, PJ

GREPIONI, F

JOHNSON, BFG

LEWIS, J

SABATINO, P

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND

[2] UNIV BOLOGNA,DIPARTIMENTO CHIM G CIAMICIAN,I-40126 BOLOGNA,ITALY

[3] UNIV EDINBURGH,DEPT CHEM,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 02期

关键词：

D O I：

10.1039/c39920000177

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two isomers of a benzene-coordinated pentaruthenium-carbido cluster, [Ru5C(CO)12(mu(3):eta(2):eta(2):eta(2)-C6H5)] 1 and [Ru5C(CO)12(eta(6)-C6H6)] 2 have been synthesised from [Ru5C(CO)15] 3 and structrally characterised by single crystal X-ray diffraction; 1 is irreversibly converted to 2 on mild thermolysis.

引用

页码：177 / 178

页数：2

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