A COMPUTER-SIMULATION OF THE CLASSIC EXPERIMENT ON OSMOSIS AND OSMOTIC-PRESSURE

被引：75

作者：

MURAD, S ^{[1
]}

POWLES, JG ^{[1
]}

机构：

[1] UNIV KENT,PHYS LAB,CANTERBURY CT2 7NZ,KENT,ENGLAND

来源：

JOURNAL OF CHEMICAL PHYSICS | 1993年 / 99卷 / 09期

关键词：

D O I：

10.1063/1.465421

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A novel computer simulation technique for studying fluids in confined geometries has been developed and used to replicate Pfeffer's experiment on osmosis in semipermeable membranes in 1877. Our results confirm the validity of van't Hoffs famous relationship for osmotic pressure over a wide range of concentrations, and also clearly establish its validity even for molecular systems. We believe this is the first theoretical validation of this result for such a wide range of concentrations, where no explicit assumption of ideality is made for the interactions of the solute molecules.

引用

页码：7271 / 7272

页数：2