SYNTHESIS AND REACTIONS OF PHOSPHINE-METHYLSULFONYLOXYBORANE COMPLEXES

被引：20

作者：

OSHIKI, T ^{[1
]}

IMAMOTO, T ^{[1
]}

机构：

[1] CHIBA UNIV, FAC SCI, DEPT CHEM, YAYOI CHO, CHIBA 260, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1990年 / 63卷 / 10期

关键词：

D O I：

10.1246/bcsj.63.2846

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Functionalizations of the boranato group of phosphine-boranes have been investigated. Trimethylphosphine-borane readily reacted with methanesulfonic acid in dichloromethane with evolution of hydrogen. The resulting trimethylphosphine-methylsulfonyloxyborane was subjected to nucleophilic substitution reaction on the boron atom with arenethiols or secondary phosphine-boranes in the presence of NaH. The reactivities of the substitution products obtained were also investigated. A new phosphine-borane having a P-B-P-B-P-BP-B bond linkage was synthesized. © 1990 The Chemical Society of Japan.

引用

页码：2846 / 2849

页数：4

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