SYNTHESIS OF UNSATURATED 6-MEMBERED IRIDACYCLES FROM (PENTADIENYL)IRIDIUM PRECURSORS

被引：12

作者：

BLEEKE, JR ^{[1
]}

ROHDE, AM ^{[1
]}

BOORSMA, DW ^{[1
]}

机构：

[1] WASHINGTON UNIV,DEPT CHEM,ST LOUIS,MO 63130

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 03期

关键词：

D O I：

10.1021/om00027a057

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An iridacyclohexene complex, [CH2CH(Me)CH=C(Me)CH2Ir(PMe3)4]-+O3SCF3-(4), and its iridacyclohexadiene analogue, [CH=C(Me)CH=C(Me)CH2Ir(PMe3)4]-+O3SCF3-(6), have been synthesized and spectroscopically characterized. These novel unsaturated six-membered metallacycles are obtained via synthetic routes that utilize pentadienide as the source of ring carbon atoms.

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页码：970 / 974

页数：5

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