ALLYLSILANES IN ORGANIC-SYNTHESIS - HIGHLY STEREOSELECTIVE ALKYLATION OF BETA-SILYL-GAMMA-LACTONES

被引：4

作者：

DALY, MJ ^{[1
]}

PROCTER, G ^{[1
]}

机构：

[1] UNIV SALFORD,DEPT CHEM & APPL CHEM,SALFORD M5 4WT,LANCS,ENGLAND

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 41期

关键词：

D O I：

10.1016/0040-4039(95)01529-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Direct alkylation of hydroxy-lactones obtained by the diastereoselective dihydroxylation of ester-allylsilanes takes place with high diastereoselectivity without protection of the hydroxyl function.

引用

页码：7549 / 7550

页数：2

共 11 条

[1] CLARK TD, 1992, J ORG CHEM, V57, P4323
[2] THE DIASTEREOSELECTIVITY OF ELECTROPHILIC ATTACK ON TRIGONAL CARBON ADJACENT TO A STEREOGENIC CENTER - DIASTEREOSELECTIVE ALKYLATION AND PROTONATION OF OPEN-CHAIN ENOLATES HAVING A STEREOGENIC CENTER CARRYING A SILYL GROUP AT THE BETA POSITION
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[3] ALLYLSILANES IN ORGANIC-SYNTHESIS - STEREOSELECTIVE SYNTHESIS OF TRANS-ALKENE PEPTIDE ISOSTERES
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WARD, RA
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[J]. TETRAHEDRON LETTERS, 1995, 36 (41) : 7545 - 7548
[4] FLEMING I, 1992, J CHEM SOC PERK T 1, P3295, DOI 10.1039/p19920003295
[5] THE DIASTEREOSELECTIVITY OF ELECTROPHILIC ATTACK ON TRIGONAL CARBON ADJACENT TO A STEREOGENIC CENTER
FLEMING, I
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1992, (24): : 3363 - 3369
[6] ALLYLSILANES IN ORGANIC-SYNTHESIS - AN APPROACH TO THE STEREOSELECTIVE SYNTHESIS OF UNITS FOR NATURAL PRODUCT SYNTHESIS
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[J]. TETRAHEDRON LETTERS, 1990, 31 (07) : 1059 - 1062
[7] DIASTEREOSELECTIVE ELECTROPHILIC ADDITION-REACTIONS TO CHIRAL BETA-DIMETHYLPHENYLSILYL ESTER ENOLATES - SYNTHESIS OF 2,3-ANTI-ALPHA-SUBSTITUTED-BETA-SILYL-(E)-HEX-4-ENOATES
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BERESIS, R
XU, F
YANG, M
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (26) : 7341 - 7344
[8] EPOXY-SILANES IN ORGANIC-SYNTHESIS
PROCTER, G
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MURPHY, PJ
TAN, TS
MATHER, AN
[J]. TETRAHEDRON, 1988, 44 (13) : 3953 - 3973
[9] REHDERS F, 1992, SYNTHESIS-STUTTGART, P859
[10] CLAISEN REARRANGEMENTS OF ENANTIOMERICALLY PURE C3-(ACYLOXY)-(E)-VINYLSILANES
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PANEK, JS
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (10) : 3431 - 3438

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