THE EFFECT OF CETYLTRIMETHYLAMMONIUM BROMIDE ON THE 2-IODOSYL-5-OCTYLOXY-BENZOATE-CATALYZED HYDROLYSIS OF ACTIVE ESTERS AND RELATED-COMPOUNDS

被引：6

作者：

LESLIE, DR

PANTELIDIS, S

机构：

[1] Materials Research Laboratory, DSTO, Ascot Vale, VIC, 3032

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1990年 / 43卷 / 05期

关键词：

D O I：

10.1071/CH9900937

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Enhancements provided by micellized cetyltrimethylammonium bromide (ctab), to the rates of reaction between 2-iodosyl-5-octyloxybenzoic acid and 4-nitrophenyl diphenyl phosphate (3), 4-nitrophenyl acetate (4), 1-methylethyl methylphosphonofluoridate (5), 1, 2, 2-trimethylpropyl methylphosphonofluoridate (6) and ethyl N, N-dimethylphosphoramidocyanidate (7) are determined over a range of ctab concentrations. The maximum enhancements observed for substrates (5)-(7) are greater than predicted by the phase-separation model.1 The suitability of the model to describe these reactions is considered. © 1990 ASEG.

引用

页码：937 / 943

页数：7

共 10 条

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