OXIDATION OF OLIGOGLYCOSYL ALDITOLS DURING METHYLATION CATALYZED BY SODIUM-HYDROXIDE AND IODOMETHANE IN METHYL SULFOXIDE

被引：18

作者：

YORK, WS

KIEFER, LL

ALBERSHEIM, P

DARVILL, AG

机构：

[1] Complex Carbohydrate Research Center, The University of Georgia, Athens, GA 30602

来源：

CARBOHYDRATE RESEARCH | 1990年 / 208卷

关键词：

D O I：

10.1016/0008-6215(90)80097-M

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Certain artifacts in the glycosyl-linkage analysis of oligoglycosyl alditols were shown to be caused by oxidation of the alditol moieties when O-methylation was catalyzed by NaOH in Me2SO. The partially methylated alditol acetates derived from 1-[2H]-cellobiitol that was O-methylated by this method were analyzed in detail to confirm this conclusion. © 1990.

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页码：175 / 182

页数：8

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