CHEMICAL EFFECTS IN THE ASSESSMENT OF PHOSPHATE ROCK RESIDUES EXTRACTED FROM MULTICOMPONENT FERTILIZERS

被引：1

作者：

BRAITHWAITE, AC

EATON, AC

GROOM, PS

机构：

[1] Department of Scientific and Industrial Research, DSIR Chemistry, Auckland

来源：

FERTILIZER RESEARCH | 1992年 / 32卷 / 03期

关键词：

PARTIALLY ACIDULATED PHOSPHATE ROCKS; EXTRACTION METHODS; SOLUBILITY DETERMINATIONS; CONTAMINANT EFFECTS;

D O I：

10.1007/BF01050372

中图分类号：

S15 [土壤学];

学科分类号：

0903 ; 090301 ;

摘要：

Methods of obtaining "reactive" phosphate rock residues from multicomponent phosphate fertilisers which contain soluble phosphorus components have been examined. Extraction using cold neutral ammonium citrate has been found to be more suitable than water, as chemical reactions appear to occur in water extraction solutions to modify the residue, and more impurity species such as calcium sulphate and iron and aluminium phosphates remain in the residues to complicate the process of obtaining reliable solubility figures. "Deactivation" of the phosphate rock residues (as measured by decreased 2% formic acid solubilities) was found to be due to reactions occurring during the maturing process, and was dependent on the phosphate rock used, with North Carolina phosphate rock-based residues significantly affected, but Arad-based residues almost unaffected. However, for neutral ammonium citrate extractions, only North Carolina-based residues produced solubility figures lower than the original phosphate rock. Some selectivity of reaction in single superphosphate-"reactive" phosphate rock mixtures was indicated which further complicated assessment of the "deactivation" effect; however such an effect appeared to be much less significant than previously suggested.

引用

页码：343 / 350

页数：8

共 8 条

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