TETRACARBONYL AND PENTACARBONYL COMPOUNDS OF CHROMIUM, MOLYBDENUM AND TUNGSTEN WITH OXYGENBRIDGED AND SULFURBRIDGED DISTIBINES AND WITH CHLORODIPHENYLSTIBINE AS COMPLEX LIGANDS

被引:20
作者
WIEBER, M
GRAF, N
机构
来源
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1993年 / 619卷 / 12期
关键词
PENTACARBONYL(DIORGANOSTIBINE)CHROMIUM; -MOLYBDENUM; -TUNGSTEN COMPLEXES; TETRACARBONYL(DIORGANOSTIBINE)CHROMIUM AND -MOLYBDENUM COMPLEXES;
D O I
10.1002/zaac.19936191206
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The penta- and tetracarbonyl complexes of chromium, molybdenum and tungsten with the stibines Ph2SbCl and (Ph2Sb)2X (X = O and S) are obtained by photochemical reaction of the hexacarbonyls in thf and by thermic ligand substitution of (eta4-C7H8)M(CO)4 (M = Cr, Mo) with stibines. In the case of (Ph2Sb)2X monodentate or bidentate coordination is possible.
引用
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页码:1991 / 1997
页数:7
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