TETRACARBONYL AND PENTACARBONYL COMPOUNDS OF CHROMIUM, MOLYBDENUM AND TUNGSTEN WITH OXYGENBRIDGED AND SULFURBRIDGED DISTIBINES AND WITH CHLORODIPHENYLSTIBINE AS COMPLEX LIGANDS

被引：20

作者：

WIEBER, M

GRAF, N

机构：

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1993年 / 619卷 / 12期

关键词：

PENTACARBONYL(DIORGANOSTIBINE)CHROMIUM; -MOLYBDENUM; -TUNGSTEN COMPLEXES; TETRACARBONYL(DIORGANOSTIBINE)CHROMIUM AND -MOLYBDENUM COMPLEXES;

D O I：

10.1002/zaac.19936191206

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The penta- and tetracarbonyl complexes of chromium, molybdenum and tungsten with the stibines Ph2SbCl and (Ph2Sb)2X (X = O and S) are obtained by photochemical reaction of the hexacarbonyls in thf and by thermic ligand substitution of (eta4-C7H8)M(CO)4 (M = Cr, Mo) with stibines. In the case of (Ph2Sb)2X monodentate or bidentate coordination is possible.

引用

页码：1991 / 1997

页数：7

共 10 条

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