VIBRONIC INTENSITIES IN THE ELECTRONIC-SPECTRA OF TRANSITION-METAL COMPLEX-IONS .7. THE GAMMA-8(2T2G)-]GAMMA 8 (4A2G) ELECTRONIC-TRANSITION OF THE REBR26- ION IN CS2ZRBR6

被引：4

作者：

ACEVEDO, R ^{[1
]}

DIAZ, G ^{[1
]}

LETELIER, JR ^{[1
]}

FLINT, CD ^{[1
]}

机构：

[1] UNIV LONDON,BIRKBECK COLL,DEPT CHEM,LASER LAB,LONDON WC1H 0PP,ENGLAND

来源：

MOLECULAR PHYSICS | 1990年 / 71卷 / 05期

关键词：

D O I：

10.1080/00268979000102321

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The vibronic intensities of the vibronic origins due to the three odd-parity vibrational modes of the GAMMA-8(2T2g) --> GAMMA-8(4A2g) electronic transition of the ReBr6(2-) ion are calculated using both crystal-field and ligand-polarization vibronic models. The crystal-field calculations is carried out using the closure approximation, and both models employ the double-group formalism. The vibronic intensity distribution is different for the two models, but by using reasonable values of the radial integrals and atomic charges, satisfactory agreement with experiment is achieved.

引用

页码：1063 / 1073

页数：11

共 21 条

[1] VIBRONIC INTENSITIES IN THE ELECTRONIC-SPECTRA OF TRANSITION-METAL IONS .2. LIGAND POLARIZATION CALCULATIONS FOR THE 2EG REVERSIBLE 4A2G TRANSITIONS OF MNF62- [J].