SULFONYL ESTERS .6. ELUCIDATION OF THE FIRST SEQUENCE IN THE TRITHIOORTHOFORMATE REACTION

被引：3

作者：

BAUM, JC

BLACK, BE

PRECEDO, L

GOEHL, JE

LANGLER, RF

机构：

[1] MT ALLISON UNIV,DEPT CHEM,SACKVILLE,NB E0A 3C0,CANADA

[2] FLORIDA INST TECHNOL,DEPT CHEM,MELBOURNE,FL 32901

来源：

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 1995年 / 73卷 / 03期

关键词：

SINGLE ELECTRON TRANSFER; SULFONATE ESTERS; SULFIDE-SULFONATE ESTERS;

D O I：

10.1139/v95-058

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The one-pot conversion of a mercaptan and an aryl methanesulfonate into a trithioorthoformate is described. The intermediacy of a sulfide-sulfonate ester is firmly established. Experimental and computational results permit the formulation of a possible pathway for the formation of the intermediate sulfide-sulfonate ester.

引用

页码：444 / 452

页数：9

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