KINETIC-MODELS FOR THE CHEMISORPTION OF ORGANIC-COMPOUNDS ON OXIDE SURFACES

被引：5

作者：

BOGILLO, VI

机构：

[1] Institute of Surface Chemistry, Ukrainian Academy of Sciences, Kiev

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1993年 / 50卷 / 1-2期

关键词：

D O I：

10.1007/BF02062192

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A kinetic equation for chemisorption on amorphous oxide surfaces is proposed, and activation energies, pre-exponential factors for reactions of various organosilicon compounds with Si, Ti and Al oxide active sites are calculated. Relationships between the kinetic parameters and reagent structure were established.

引用

页码：75 / 81

页数：7

共 13 条

[1]

BOGILLO VI, 1992, UKR KHIM ZH+, V58, P144

[2]

BOGILLO VI, 1992, P INT S EFFECTS SURF

[3] KINETICS OF DISSOCIATIVE CHEMISORPTION ON STRAINED EDGE-SHARED SURFACE-DEFECTS ON DEHYDROXYLATED SILICA [J].