REDUCTION OF [1.1.1]PROPELLANE WITH LITHIUM 4,4'-DI-TERT-BUTYLBIPHENYL - BICYCLO[1.1.1]PENT-1,3-DIYLDILITHIUM

被引：22

作者：

BUNZ, U ^{[1
]}

SZEIMIES, G ^{[1
]}

机构：

[1] UNIV MUNICH, INST ORGAN CHEM, KARLSTR 23, W-8000 MUNICH 2, GERMANY

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 05期

关键词：

D O I：

10.1016/S0040-4039(00)94592-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[1.1.1]Propellane 1 has been reduced by 3 to 1,3-dilithiobicyclo[1.1.1]pentane (2b). which could be converted to some 1,3-disubstituted derivatives of 2a The reduction was also achieved with propellane 5. In addition, the synthesis oF the dialkyne 2i is reported. © 1990.

引用

页码：651 / 652

页数：2

共 20 条

[1] POLAR SUBSTITUENT EFFECTS IN 1,3-DISUBSTITUTED BICYCLO[1.1.1]PENTANES [J].

APPLEQUIST, DE ;

RENKEN, TL ;

WHEELER, JW .

JOURNAL OF ORGANIC CHEMISTRY, 1982, 47 (25) :4985-4995

[2] SYNTHESES OF [1.1.1]PROPELLANES [J].

BELZNER, J ;

GAREISS, B ;

POLBORN, K ;

SCHMID, W ;

SEMMLER, K ;

SZEIMIES, G .

CHEMISCHE BERICHTE, 1989, 122 (08) :1509-1529

[3] CONCERNING THE SYNTHESIS OF [1.1.1]PROPELLANE [J].

BELZNER, J ;

BUNZ, U ;

SEMMLER, K ;

SZEIMIES, G ;

OPITZ, K ;

SCHLUTER, AD .

CHEMISCHE BERICHTE, 1989, 122 (02) :397-398

[4] TETRACYCLO[5.1.0.0/1,6/0/2,7]OCTANE - SOME UNEXPECTED ADDITION-REACTIONS AND A NEW SYNTHESIS [J].

BELZNER, J ;

SZEIMIES, G .

TETRAHEDRON LETTERS, 1987, 28 (27) :3099-3102

[5]

BOTHE HS, 1988, AM CHEM SOC, V29, P412

[6] BRIDGEHEAD-COUPLED BICYCLO[1.1.1]PENTANES - SYNTHESIS AND STRUCTURE [J].

BUNZ, U ;

POLBORN, K ;

WAGNER, HU ;

SZEIMIES, G .

CHEMISCHE BERICHTE-RECUEIL, 1988, 121 (10) :1785-1790

[7] SYNTHESIS OF 1-ALKYNYLBICYCLO[1.1.1]PENTANES [J].

BUNZ, U ;

SZEIMIES, G .

TETRAHEDRON LETTERS, 1989, 30 (16) :2087-2088

[8] ALKYLLITHIUM REAGENTS FROM ALKYL-HALIDES AND LITHIUM RADICAL-ANIONS [J].

FREEMAN, PK ;

HUTCHINSON, LL .

JOURNAL OF ORGANIC CHEMISTRY, 1980, 45 (10) :1924-1930

[9] TOWARDS A MOLECULAR-SIZE CONSTRUCTION SET - 3,3(N-1)-BISACETYLTHIO[N]STAFFANES [J].

FRIEDLI, AC ;

KASZYNSKI, P ;

MICHL, J .

TETRAHEDRON LETTERS, 1989, 30 (04) :455-458

[10] A PRACTICAL PHOTOCHEMICAL-SYNTHESIS OF BICYCLO[1.1.1]PENTANE-1,3-DICARBOXYLIC ACID [J].

KASZYNSKI, P ;

MICHL, J .

JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (19) :4593-4594

← 1 2 →