ORGANOMETALLIC DERIVATIVES OF DIPHOSPHINOAMINES, X2PN(R)PX2 - REACTIONS WITH CARBONYL DERIVATIVES OF GROUP-6 METALS AND IRON PENTACARBONYL - THE CRYSTAL-STRUCTURES OF [MO(CO)4PHN(P(OPH)2)2] AND [W(CO)4-ISO-PRN(PPH2)2]

被引：80

作者：

BALAKRISHNA, MS

PRAKASHA, TK

KRISHNAMURTHY, SS

SIRIWARDANE, U

HOSMANE, NS

机构：

[1] INDIAN INST SCI, DEPT INORGAN & PHYS CHEM, BANGALORE 560012, KARNATAKA, INDIA

[2] SO METHODIST UNIV, DEPT CHEM, DALLAS, TX 75275 USA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 390卷 / 02期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0022-328X(90)85032-T

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The diphosphinoamines X2PN(R)PX2 (L) (R = Me or Ph, X = OCH2CF3 or OPh; R = Ph, X = OC6H4Br-p; R = iPr, X = Ph) react with group 6 metal carbonyl derivatives to yield the cis-chelate complexes [M(CO)4(L-PP′)]. The structures of cis-[Mo(CO)4PhN(P(OPh)2)2] (3d) and cis-[W(CO)4iPrN(PPh2)2] (4f) have been established by single crystal X-ray diffraction studies. Reactions with iron pentacarbonyl yield complexes in which a chelating or a bridged-bidentate mode of coordination of the ligands is observed. © 1990.

引用

页码：203 / 216

页数：14

共 36 条

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