THE 1ST CATIONIC HETEROBINUCLEAR COMPLEXES WITH BRIDGING S2CPR3 LIGANDS - X-RAY STRUCTURE OF [(ETA-6-C6ME6)RU(MU-CL)(MU-S2CPCY3)W(CO)3]PF6.CH2CL2

被引：21

作者：

CUYAS, J ^{[1
]}

MIGUEL, D ^{[1
]}

PEREZMARTINEZ, JA ^{[1
]}

RIERA, V ^{[1
]}

GARCIAGRANDA, S ^{[1
]}

机构：

[1] UNIV OVIEDO,DEPT QUIM FIS & ANALIT,E-33071 OVIEDO,SPAIN

来源：

POLYHEDRON | 1992年 / 11卷 / 20期

关键词：

D O I：

10.1016/S0277-5387(00)80245-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complexes [eta6-C6Me6)Ru(mu-Cl)(mu-S2CPCy3)M(CO)3]+, which are the first examples of cationic heterobinuclear complexes containing S2CPR3 bridges, and also the first to contain S2CPR3 ligands acting as eta3(S,C,S') ligand towards a metal other than molybdenum or manganese, have been prepared by reaction of [(eta6-C6Me6)Ru(S2CPCy3) Cl]PF6 with [M(CO)3(NCR)3] (M = Mo, W), and shown to be stable enough to maintain the dinuclear unit through several reactions involving the displacement of CO.

引用

页码：2713 / 2716

页数：4

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