STEREOSELECTIVE ADDITION OF CF(3)SIME(3) ON AZIRINES - SYNTHESIS OF (E)-AZIRIDINES

被引：46

作者：

FELIX, CP ^{[1
]}

KHATIMI, N ^{[1
]}

LAURENT, AJ ^{[1
]}

机构：

[1] UNIV LYON 1,CNRS,CHIM ORGAN LAB 3,F-69622 VILLEURBANNE,FRANCE

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 20期

关键词：

TRIFLUOROMETHYLTRIMETHYLSILANE; AZIRINES; STEREOSELECTIVE ADDITION;

D O I：

10.1016/S0040-4039(00)76891-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The original use of CF(3)SiMe(3) on a carbon nitrogen double bond is described. Azirines provide (E)-aziridines.

引用

收藏

页码：3303 / 3304

页数：2

相关论文

共 8 条

[1] DERMER OC, 1969, ETHYLENIMINE OTHER A, P394
[2] FELIX C, 1991, J CHEM RES, pS32
[3] FELIX C, 1991, J CHEM RES, pM301
[4] HASSNER A, 1983, SMALL RING HETEROCYC, P54
[5] PREPARATION OF TRIFLUOROMETHYL AND OTHER PERFLUOROALKYL COMPOUNDS WITH (PERFLUORALKYL)TRIMETHYLSILANES
KRISHNAMURTI, R
BELLEW, DR
PRAKASH, GKS
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (03) : 984 - 989
[6] OLAH GA, 1992, SYNTHETIC FLUORINE C, P227
[7] SYNTHETIC METHODS AND REACTIONS .141. FLUORIDE-INDUCED TRIFLUOROMETHYLATION OF CARBONYL-COMPOUNDS WITH TRIFLUOROMETHYLTRIMETHYLSILANE (TMS-CF3) - A TRIFLUOROMETHIDE EQUIVALENT
PRAKASH, GKS
KRISHNAMURTI, R
OLAH, GA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (01) : 393 - 395
[8] SYNTHESIS OF SECONDARY AZIRIDINES SUBSTITUTED BY A TRIFLUOROMETHYL GROUP
QUINZE, K
LAURENT, A
MISON, P
FAURE, R
[J]. JOURNAL OF FLUORINE CHEMISTRY, 1989, 44 (02) : 211 - 232