SYNTHESIS AND CHARACTERIZATION OF NEW PHTHALOCYANINES PERIPHERALLY FUSED TO 4 13-MEMBERED TETRATHIAMACROCYCLES

被引：58

作者：

GUREK, AG

BEKAROGLU, O

机构：

[1] ISTANBUL TECH UNIV,DEPT CHEM,MASLAK 80626,TURKEY

[2] TUBITAK MARMARA RES CTR,DEPT CHEM,GEBZE 41470,TURKEY

来源：

HELVETICA CHIMICA ACTA | 1994年 / 77卷 / 06期

关键词：

D O I：

10.1002/hlca.19940770618

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The new metal-free phthalocyanine 5 and phthalocyaninatometals 6-8 (M=Co, Ni, or Zn) fused in peripheral positions with four 13-membered tetrathiamacrocycles were prepared by cyclotetramerization of 2,3,6,7,9,10-hexa-hydro-5H-[1,4,8,11] benzotetrathiacyclotridecine-13,14-dicarbonitrile in the presence of a suitable metal salt or a strong organic base. In contrast to the aza- or oxamacrocycle-fused analogs, the solubility of these phthalocyanines is very low. Complexation of the tetrathiamacrocycles of 7 and 8 with Pd-II or Ag-I to form pentanuclear products was accomplished from their suspensions.

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页码：1616 / 1622

页数：7

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