A STUDY OF THE F2-DELTA RYDBERG STATE OF NS BY RESONANCE-ENHANCED MULTIPHOTON-IONIZATION SPECTROSCOPY

被引:6
作者
BARNES, M [1 ]
BAKER, J [1 ]
DYKE, JM [1 ]
RICHTER, R [1 ]
机构
[1] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO9 5NH,HANTS,ENGLAND
关键词
D O I
10.1016/0009-2614(91)80237-R
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The F2-DELTA state of NS has been observed as a two-photon resonance in the overall three-photon MPI spectrum recorded for this molecule in the single-photon wavelength range 337-365 nm. The state is Rydberg in character and arises from the electronic excitation ... 7-sigma-22-pi-43d-delta-1 <-- ... 7-sigma-22-pi-43-pi-1. Analysis of the spectra has yielded vibrational and rotational constants for the F2-DELTA state which are consistent with its Rydberg character.
引用
收藏
页码:433 / 439
页数:7
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