CARBON-CARBON BOND FORMATION BY INTERMOLECULAR RADICAL REACTION - SMI2-PROMOTED CARBONYL-ALKYNE REDUCTIVE COUPLING

被引：30

作者：

INANAGA, J ^{[1
]}

KATSUKI, J ^{[1
]}

UJIKAWA, O ^{[1
]}

YAMAGUCHI, M ^{[1
]}

机构：

[1] KYUSHU UNIV,DEPT CHEM,FUKUOKA 812,JAPAN

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 37期

关键词：

D O I：

10.1016/S0040-4039(00)93497-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient intermolecular carbonyl-alkyne reductive coupling reaction was realized for the first time by using the system, Sml2-HMPA-hydrogen donor, to give the corresponding allylic alcohols in good yields.

引用

页码：4921 / 4924

页数：4

共 15 条

[1] THE DESIGN AND APPLICATION OF FREE-RADICAL CHAIN REACTIONS IN ORGANIC-SYNTHESIS .1.
CURRAN, DP
[J]. SYNTHESIS-STUTTGART, 1988, (06): : 417 - 439
[2] THE DESIGN AND APPLICATION OF FREE-RADICAL CHAIN REACTIONS IN ORGANIC-SYNTHESIS .2.
CURRAN, DP
[J]. SYNTHESIS-STUTTGART, 1988, (07): : 489 - 513
[3] ADDITION OF ALKYL RADICALS TO ALKYNES - DISTINCTION BETWEEN RADICAL AND IONIC NUCLEOPHILES
GIESE, B
LACHHEIN, S
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1982, 21 (10): : 768 - &
[4] FORMATION OF CC BONDS BY ADDITION OF FREE-RADICALS TO ALKENES
GIESE, B
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1983, 22 (10): : 753 - 764
[5] Giese B., 1986, RADICALS ORGANIC SYN
[6] NEGATIVE-IONS - EFFECT OF ALPHA-SILYL VS BETA-SILYL SUBSTITUTION ON THE NEGATIVE-ION STATES OF PI-SYSTEMS
GIORDAN, JC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (22) : 6544 - 6546
[7] INANAGA J, UNPUB
[8] ELECTRON-SPIN RESONANCE STUDY OF INVERSION AND CONFORMATIONS IN 1-HYDROXYCYCLOHEXYL RADICALS
LLOYD, RV
CAUSEY, JG
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1981, (08): : 1143 - 1147
[9] INTRAMOLECULAR REDUCTIVE COUPLING REACTIONS PROMOTED BY SAMARIUM DIIODIDE
MOLANDER, GA
KENNY, C
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (21) : 8236 - 8246
[10] SMI2-INDUCED REDUCTIVE CROSS-COUPLING OF CARBONYL-COMPOUNDS WITH ALPHA,BETA-UNSATURATED ESTERS
OTSUBO, K
INANAGA, J
YAMAGUCHI, M
[J]. TETRAHEDRON LETTERS, 1986, 27 (47) : 5763 - 5764

← 1 2 →