FIRST RESOLUTION OF A LINEAR CHELATING TETRA(TERTIARY PHOSPHINE) - RESOLUTION AND ABSOLUTE-CONFIGURATIONS OF ENANTIOMERS OF (R-ASTERISK,R-ASTERISK)-(+/-)-1,1,4,7,10,10-HEXAPHENYL-1,4,7,10-TETRAPHOSPHADECANE

被引：25

作者：

AIREY, AL ^{[1
]}

SWIEGERS, GF ^{[1
]}

WILLIS, AC ^{[1
]}

WILD, SB ^{[1
]}

机构：

[1] AUSTRALIAN NATL UNIV,INST ADV STUDIES,RES SCH CHEM,CANBERRA,ACT 0200,AUSTRALIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 06期

关键词：

D O I：

10.1039/c39950000693

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The important and commercially available linear tetra(tertiary phosphine) (R*,R*)-(+/-)/ (R*,S*)-Ph(2)PCH(2)CH(2)P(Ph)CH2CH2P(Ph)CH(2)CH(2)PPh(2) has been separated into diastereoisomers and the (R*,R*)-(+/-)-diastereoisomer resolved by the method of metal complexation giving the first optically active tetra(tertiary phosphine).

引用

页码：693 / 694

页数：2

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